SURFACE DIFFUSION AND ANISOTROPIC LATERAL INTERACTIONS

A.V. Myshlyavtsev, V.P. Zhdanov and P.R. Norton
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A.V. Myshlyavtsev: Institute of Catalysis, Novosibirsk 630090, Russia
V.P. Zhdanov: Institute of Catalysis, Novosibirsk 630090, Russia;
P.R. Norton: Interface Science Western, Department of Physics and Chemistry, University of Western Ontario, London, Ontario, Canada N6A 3K7, Canada

Surface Review and Letters (SRL), 1996, vol. 03, issue 03, 1417-1420

Abstract: Anisotropic lateral interactions between particles on a rectangular lattice result in anisotropy in the coverage dependence of the chemical diffusion coefficient. This effect is studied in the framework of the lattice-gas model taking into account repulsive lateral interactions in the ground state and also lateral interactions in the activated state. To calculate the diffusion coefficient, the transfer-matrix technique is employed.

Date: 1996
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DOI: 10.1142/S0218625X96002436

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