CHEMISTRY ON SINGLE CRYSTAL SURFACES OFPtANDPdALLOYS

B. E. Nieuwenhuys
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B. E. Nieuwenhuys: Leiden Institute of Chemistry, Gorlaeus Laboratories, PO Box 9502, 2300 RA Leiden, The Netherlands

Surface Review and Letters (SRL), 1996, vol. 03, issue 05n06, 1869-1888

Abstract: During the past decade, alloy surfaces have been increasingly studied on the atomic level. As a result, their atomic structure, composition and the adsorbate-surface interactions are much better understood. The purpose of this paper is to review the status of our present knowledge of the chemical properties of single crystal surfaces of Pd and Pt alloys. In particular, the adsorption ofH2,02, CO, NO and the catalytic reactions involving these molecules on single crystal surfaces ofPd-Cu,Pd-Ag,Pd-Au,Pt-Cu,Pt-Rh,Pt-Fe,Pt-Co,Pt-NiandPt-Tiare discussed and compared with the processes on the corresponding single crystal surfaces of the pure metals.

Date: 1996
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DOI: 10.1142/S0218625X96002795

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