STRUCTURE CHANGES FORCu(111)/LiOBSERVED VIA DISCRETE QUANTUM WELL STATES
A. Carlsson,
D. Claesson,
G. Katrich,
S.-Å Lindgren and
L. Walldén
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A. Carlsson: Physics Department, Chalmers University of Technology, 41296 Göteborg, Sweden
D. Claesson: Physics Department, Chalmers University of Technology, 41296 Göteborg, Sweden
G. Katrich: Physics Department, Chalmers University of Technology, 41296 Göteborg, Sweden;
S.-Å Lindgren: Physics Department, Chalmers University of Technology, 41296 Göteborg, Sweden
L. Walldén: Physics Department, Chalmers University of Technology, 41296 Göteborg, Sweden
Surface Review and Letters (SRL), 1997, vol. 04, issue 06, 1233-1237
Abstract:
Via photoemission in the near UV from discrete quantum well states, four different types of atom rearrangements are observed forCu(111)/Li. In the monolayer range a gradual energy shift reflects a gradual compression of the Li layer as more atoms are adsorbed. The onset of Li substitution and formation of a(2×2)structure when, at RT, monolayer Li coverage is exceeded is monitored via the appearance of a quantum well state characteristic of the new phase. A small energy shift indicates that, if it is cooled (170 K), the new structure is unstable with respect to Li adsorption. Finally, an energy downshift with increasing coverage observed for a state characteristic of 2 ML Li is ascribed to an increasing area for one-atomic-layer-high islands formed by Li atoms on top of the first full layer.
Date: 1997
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DOI: 10.1142/S0218625X97001590
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