TRANSFORMATION OF THE ELECTRONIC STRUCTURE OFCuINTOCu2OIN THE ADSORPTION OF OXYGEN

V. P. Belash, I. N. Klimova, V. I. Kormilets, V. Yu. Trubitsin and L. D. Finkelstein
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V. P. Belash: Physico-Technical Institute, Russian Academy of Sciences, Ural Branch, Kirov str. 132, Izhevsk 426001, Russia
I. N. Klimova: Physico-Technical Institute, Russian Academy of Sciences, Ural Branch, Kirov str. 132, Izhevsk 426001, Russia
V. I. Kormilets: Physico-Technical Institute, Russian Academy of Sciences, Ural Branch, Kirov str. 132, Izhevsk 426001, Russia
V. Yu. Trubitsin: Physico-Technical Institute, Russian Academy of Sciences, Ural Branch, Kirov str. 132, Izhevsk 426001, Russia
L. D. Finkelstein: Institute of Metal Physics, Russian Academy of Sciences, Ural Branch, S. Kovalevskaya str. 18, Ekaterinburg 620219, Russia

Surface Review and Letters (SRL), 1999, vol. 06, issue 03n04, 383-388

Abstract: Systematic photoelectron-spectroscopy studies of the oxygen adsorption on a polycrystalline copper in a wide range of oxygen exposures allowed us to trace the step-by-step transformation of the electronic structure of pure Cu into the electronic structure ofCu2O. With the use of the density-of-states calculations implemented by the full-potential linear muffin-tin-orbital method, the interpretation of a number of features in the photoelectron spectra and their behavior with the increase of oxygen exposure was carried out. It was also shown that copper-surface oxidation proceeds in three main steps.

Date: 1999
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DOI: 10.1142/S0218625X9900038X

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