NUCLEAR MOTION, SYMMETRY BREAKING AND DISSOCIATION DYNAMICS OF CORE-EXCITED POLYATOMIC MOLECULES

Kiyoshi Ueda ()
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Kiyoshi Ueda: Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577, Japan

Surface Review and Letters (SRL), 2002, vol. 09, issue 01, 21-29

Abstract: Recent studies on nuclear dynamics of core-excited and Auger final states are reviewed. Emphasis is given to the nuclear motion of the core-excited states and its influence to the subsequent decay and fragmentation processes. As specific examples we discuss two-dimensional nuclear motion caused by the O1s → 2b2excitation inH2Oand by the C1s → 2πuexcitation inCO2, as well as out-of-plane motion caused by B$1s\to 2a_2^{\prime\prime}$excitation and asymmetric stretching motion caused by the F1sionization inBF3.

Date: 2002
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DOI: 10.1142/S0218625X02001756

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