SYMMETRY BREAKING OF ASiF4MOLECULE BY F1sEXCITATION

Kazumasa Okada, Yusuke Tamenori, Inosuke Koyano and Kiyoshi Ueda
Additional contact information
Kazumasa Okada: Department of Chemistry, Hiroshima University, Higashi-Hiroshima 739-8526, Japan
Yusuke Tamenori: SPring-8/Japan Synchrotron Radiation Research Institute, Mikazuki, Hyogo 679-5198, Japan
Inosuke Koyano: Department of Material Science, Himeji Institute of Technology, Kamigori, Hyogo 678-1297, Japan
Kiyoshi Ueda: Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Sendai 980-8577, Japan

Surface Review and Letters (SRL), 2002, vol. 09, issue 01, 89-92

Abstract: Angle-resolved ion yield spectroscopy revealed that ionic fragmentation of aTdsymmetry moleculeSiF4is anisotropic after F1sphotoexcitation. The anisotropic fragmentation is interpreted as being due to preferential bond rupture at the F1score-hole site. The probability of the bond rupture at the core-hole site is three times as large as those at other sites. The origin of the preferential bond rupture is discussed in terms of symmetry breaking due to dynamical core-hole localization.

Date: 2002
References: Add references at CitEc
Citations:

Downloads: (external link)
http://www.worldscientific.com/doi/abs/10.1142/S0218625X02001999
Access to full text is restricted to subscribers

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:wsi:srlxxx:v:09:y:2002:i:01:n:s0218625x02001999

Ordering information: This journal article can be ordered from

DOI: 10.1142/S0218625X02001999

Access Statistics for this article

Surface Review and Letters (SRL) is currently edited by S Y Tong

More articles in Surface Review and Letters (SRL) from World Scientific Publishing Co. Pte. Ltd.
Bibliographic data for series maintained by Tai Tone Lim ().