X-RAY ABSORPTION EVIDENCE FOR THE BACK-DONATION IN IRON CYANIDE COMPLEXES

A. S. Vinogradov, A. B. Preobrajenski, S. A. Krasnikov, T. Chassé, R. Szargan, A. Knop-Gericke, R. Schlögl and P. Bressler
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A. S. Vinogradov: Institute of Physics, St. Petersburg State University, St. Petersburg, 198504, Russia
A. B. Preobrajenski: W.-Ostwald-Institut für Physikalische und Theoretische Chemie, Universität Leipzig, Linnéstr. 2, Leipzig, D-04103, Germany
S. A. Krasnikov: W.-Ostwald-Institut für Physikalische und Theoretische Chemie, Universität Leipzig, Linnéstr. 2, Leipzig, D-04103, Germany
T. Chassé: W.-Ostwald-Institut für Physikalische und Theoretische Chemie, Universität Leipzig, Linnéstr. 2, Leipzig, D-04103, Germany
R. Szargan: W.-Ostwald-Institut für Physikalische und Theoretische Chemie, Universität Leipzig, Linnéstr. 2, Leipzig, D-04103, Germany
A. Knop-Gericke: Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, Berlin, D-14195, Germany
R. Schlögl: Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, Berlin, D-14195, Germany
P. Bressler: BESSY GmbH, Albert-Einstein-Str. 15, Berlin, D-12489, Germany

Surface Review and Letters (SRL), 2002, vol. 09, issue 01, 359-364

Abstract: High-resolution, uniformly calibrated Fe2p3/2absorption spectra of various Fe(II) and Fe(III) compounds with the metal atom octahedrally coordinated to atomic and molecular ligands are analyzed expecting changes in the absorption spectra due to differences in the formal valence state and in the character of the chemical bond. Particular attention is given to revealing spectral characteristics of the3dπ–2π(π*)charge transfer (π-back-donation effect) between the iron atom and cyanide ligands.

Date: 2002
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DOI: 10.1142/S0218625X02002270

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