THEORY OF POLARIZATION DEPENDENCE IN RESONANT X-RAY EMISSION SPECTRA OF A URANIUM COMPOUND

Makoto Nakazawa (), Haruhiko Ogasawara and Akio Kotani
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Makoto Nakazawa: Japan Synchrotron Radiation Research Institute (JASRI), SPring-8, Mikazuki, Sayo, Hyogo 679-5198, Japan
Haruhiko Ogasawara: Institute for Solid State Physics, The University of Tokyo, Kashiwanoha, Kashiwa, Chiba 277-8581, Japan
Akio Kotani: Institute for Solid State Physics, The University of Tokyo, Kashiwanoha, Kashiwa, Chiba 277-8581, Japan

Surface Review and Letters (SRL), 2002, vol. 09, issue 02, 1149-1153

Abstract: We calculate the U5f → 3d5/2resonant X-ray emission spectra (5f → 3d5/2RXES) of a uranium compound,UO3, by means of the Anderson impurity model with full multiplet effects. The calculation is based on the second-order optical formula, and the effect of the X-ray polarization is taken into account. The calculated results of5f → 3d5/2RXES show the strong dependence on the X-ray polarization. Using the selection rule of the dipole transition with polarized X-rays, the calculated spectral features are explained.

Date: 2002
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DOI: 10.1142/S0218625X02003433

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