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EFFECT OF GRAIN SIZE ON THE ELECTRON WORK FUNCTION OFCuANDAl

Wen Li and D. Y. Li
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Wen Li: Changchun University, P. R. China
D. Y. Li: Department of Chemical and Materials Engineering, University of Alberta, Edmonton, Alberta, Canada T6G 2G6, Canada

Surface Review and Letters (SRL), 2004, vol. 11, issue 02, 173-178

Abstract: The Kelvin probe is a sophisticated instrument which is very sensitive to changes in surface conditions, such as deformation, texture, phase transformation and contamination. Efforts have been made to use this technique to diagnose wear. In this study, the effect of the grain boundary (GB) on the electron work function (EWF) was examined with the aim of investigating the contribution of changes in grain size to total changes in the EWF during wear. Copper and aluminum were studied as examples. It was demonstrated that the EWF dropped in the vicinity of GB's and the mean EWF decreased as the grain size decreased. The mechanism responsible for the changes in the EWF with respect to the GB is discussed.

Keywords: Grain size; work function; Kelvin probe (search for similar items in EconPapers)
Date: 2004
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DOI: 10.1142/S0218625X04006025

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