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STUDY OF COLORATION ON EXCIMER LASER TREATED TITANIUM SURFACES

H. X. Qian, Wei Zhou () and H. Y. Zheng
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H. X. Qian: Shenzhen Key Laboratory of Special Functional Materials, Shenzhen University, Shenzhen 518060, P. R. China
Wei Zhou: Precision Engineering and Nanotechnology Centre, School of Mechanical and Aerospace Engineering, Nanyang Technological University, 50 Nanyang Avenue, Singapore 639798, Singapore
H. Y. Zheng: Singapore Institute of Manufacturing Technology, 71 Nanyang Drive, Singapore 638075, Singapore

Surface Review and Letters (SRL), 2008, vol. 15, issue 05, 675-679

Abstract: Surface oxidation ofTiwas carried out using KrF excimer laser in the presence ofO2. Different colors were obtained by varying the number of laser pulses at the fixed laser fluence. X-ray photoelectron spectroscopy shows that the outmost surface is composed ofTiO2and the inner layer consists ofTiOandTi2O3as well asTiO2. Fractions of titanium chemical states stabilized at 33%TiO, 63%TiO2, and 2%Ti2O3with increasing number of laser pulses. The surface roughness tends to increase with number of laser pulses. It is suggested that compositional variation and morphological difference contribute to the laser-induced surface coloration.

Keywords: Titanium; excimer laser; X-ray photoelectron spectroscopy; oxidation; coloration (search for similar items in EconPapers)
Date: 2008
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DOI: 10.1142/S0218625X08011846

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