STUDIES ON CORROSION BEHAVIOR OF POLISHED NICKEL SURFACE WITH RESIN WETTED BY DEEP EUTECTIC SOLVENT

Yafei Liu (), Lishi Wang, Zhigang Lv (), Zhixiang Bu () and Xinbin Hu ()
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Yafei Liu: Hubei Provincial Key Laboratory of Green Materials of Light Industry, College of Materials and Chemical Engineering, Hubei University of Technology, Wuhan 430068, P. R. China
Lishi Wang: Hubei Provincial Key Laboratory of Green Materials of Light Industry, College of Materials and Chemical Engineering, Hubei University of Technology, Wuhan 430068, P. R. China
Zhigang Lv: Hubei Provincial Key Laboratory of Green Materials of Light Industry, College of Materials and Chemical Engineering, Hubei University of Technology, Wuhan 430068, P. R. China
Zhixiang Bu: Hubei Provincial Key Laboratory of Green Materials of Light Industry, College of Materials and Chemical Engineering, Hubei University of Technology, Wuhan 430068, P. R. China
Xinbin Hu: Hubei Provincial Key Laboratory of Green Materials of Light Industry, College of Materials and Chemical Engineering, Hubei University of Technology, Wuhan 430068, P. R. China

Surface Review and Letters (SRL), 2023, vol. 30, issue 05, 1-13

Abstract: As a material widely used in aerospace and energy development, the surface quality of nickel and its alloy will need to be improved urgently. Electrochemical polishing, as a surface treatment method, can smoothen the metal surface and improve its corrosion resistance. Strict environmental regulations have given rise to new electrochemical polishing techniques. In this paper, the electrochemical polishing of nickel was carried out using resin particles wetted by deep eutectic solvent (DES) as polishing medium. The surface morphology and roughness of polished nickel were characterized by scanning electron microscopy (SEM) and optical profilometer. In addition, electrochemical polarization curve and electrochemical impedance spectroscopy (EIS) were used to test the corrosion behavior of polished specimens in 3.5wt.% NaCl solution. The results show that the surface morphology of polished nickel shows grain boundary characteristics. The surface roughness Ra can be reduced from 0.612μm to 0.0913μm (under 30V voltage polishing 1h), and the corrosion current density can be reduced from 27.30μAcm−2 to 12.15μAcm−2. Pitting potential in the polarization curve indicates that the pits at the grain boundaries are corroded due to the influx of corrosive chloride ions. This polishing method combines the resin with DES which can reduce the production of polishing liquid waste while avoiding the use of harmful acid-base electrolytes and effectively reduce the surface geometry uneven degree, improving the surface corrosion resistance.

Keywords: Nickel; electrochemical polishing; polarization curve; electrochemical impedance spectroscopy; corrosion behavior (search for similar items in EconPapers)
Date: 2023
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DOI: 10.1142/S0218625X23500324

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