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HYDROPHOBIC PHOTORESPONSIVE AZOBENZENE-CONTAINING MATERIALS PREPARED BY CLICK REACTION

Lu Qiu, Junyu Zheng, Xinyi Yu, Xiaoqian Han and Nong Wang
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Lu Qiu: School of Chemistry and Chemical Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P. R. China
Junyu Zheng: School of Chemistry and Chemical Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P. R. China
Xinyi Yu: School of Chemistry and Chemical Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P. R. China
Xiaoqian Han: School of Chemistry and Chemical Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P. R. China
Nong Wang: School of Chemistry and Chemical Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P. R. China

Surface Review and Letters (SRL), 2024, vol. 31, issue 07, 1-12

Abstract: With the rapid development of intelligent materials in recent years, intelligent hydrophobic materials have become a new research direction, and hydrophobic surfaces with adjustable wettability have enormous application potential in many fields. Generally speaking, surface wettability is determined by the combined effect of surface chemical composition and surface morphology. Therefore, the photoresponsive wettability of azobenzene-modified surfaces can be achieved by constructing rough surface of micro-nano scale and reducing the surface free energy. In this paper, we synthesized two photo responsive hydrophobic azobenzene derivatives (AAAB-PFDT and UAAB-PFDT), characterized their structure, thermal degradation behavior, and microscopic morphology. The light conversion performance of the two materials in dispersion was also studied using a UV–Vis spectrometer. By depositing the materials on the glass slide, the measurements of the water contact angle (WCA) under different lighting conditions were performed, demonstrating that both materials exhibit excellent photoswitchable hydrophobicity and reversibility.

Keywords: Hydrophobic; azobenzene; photoresponsive materials (search for similar items in EconPapers)
Date: 2024
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DOI: 10.1142/S0218625X24500550

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