Efficient base-catalyzed decomposition and in situ hydrogenolysis process for lignin depolymerization and char elimination

Jinxing Long, Ying Xu, Tiejun Wang, Zhengqiu Yuan, Riyang Shu, Qi Zhang and Longlong Ma

Applied Energy, 2015, vol. 141, issue C, 70-79

Abstract: Serious char formation caused by the repolymerization of unsaturated decomposition products is a considerable challenge for current lignin utilization. Here, a novel and efficient base-catalyzed depolymerization and in situ hydrogenolysis process for lignin decomposition and char elimination was proposed using the synergic catalyst of NaOH coordinated with Ru/C. In which, lignin was first depolymerized to phenolic monomer and its oligomer, and then the oligomer was further converted to more stable aliphatic alcohols simultaneously. The results showed that more than 92.5% of lignin was converted, giving 12.69% phenolic monomer, 6.12% aliphatic alcohol and less than 14.03% residual solid. This residual solid selectivity was far lower than it from the single catalyst condition. Furthermore, the products were analyzed using GC–MS, GPC, HPLC–MS and 1H NMR. The synergistic effect between depolymerization and hydrogenolysis was also investigated through comparative analysis of the feedstock, products, and the recovered lignin.

Keywords: Lignin; Depolymerization; Hydrogenolysis; Phenolic; Aliphatic alcohol (search for similar items in EconPapers)
Date: 2015
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (10)

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0306261914012823
Full text for ScienceDirect subscribers only

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:appene:v:141:y:2015:i:c:p:70-79

Ordering information: This journal article can be ordered from
http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/bibliographic
http://www.elsevier. ... 405891/bibliographic

DOI: 10.1016/j.apenergy.2014.12.025

Access Statistics for this article

Applied Energy is currently edited by J. Yan

More articles in Applied Energy from Elsevier
Bibliographic data for series maintained by Catherine Liu ().