Chemical-looping auto-thermal reforming of biomass using Cu-based oxygen carrier
Haibo Zhao,
Lei Guo and
Xixian Zou
Applied Energy, 2015, vol. 157, issue C, 408-415
Abstract:
Chemical-looping reforming (CLR) of biomass, which utilizes active lattice oxygen from oxygen carrier (OC), provides a novel route to convert biomass into synthesis gas. This research utilized Cu-based OC rather than commonly-used Fe- or Ni-based OC in the process. The possible advantage is the exothermic reactions between CuO and gasification products are beneficial to auto-thermal reforming of biomass in fuel reactor. Batch fluidized bed experiments with different carriers (silica sand, Fe-based or Cu-based OCs) were conducted at different temperatures. It was found that when using Cu-based OCs, the gas yield and carbon conversion efficiency increased significantly, but the gasification efficiency and low heating value decreased accordingly, which are ascribed to the high-reactivity Cu-based OCs prompt the carbon conversion and also consume more reducible gases. The presence of Cu-based OCs help reduce C2Hm and tar in syngas. Additionally, the tar content decreased with temperature increase, while C2Hm content first increased then decreased.
Keywords: Biomass; Synthesis gas; Chemical looping reforming; Copper oxide oxygen carrier; Fluidized bed reactor (search for similar items in EconPapers)
Date: 2015
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (12)
Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0306261915005565
Full text for ScienceDirect subscribers only
Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.
Export reference: BibTeX
RIS (EndNote, ProCite, RefMan)
HTML/Text
Persistent link: https://EconPapers.repec.org/RePEc:eee:appene:v:157:y:2015:i:c:p:408-415
Ordering information: This journal article can be ordered from
http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/bibliographic
http://www.elsevier. ... 405891/bibliographic
DOI: 10.1016/j.apenergy.2015.04.093
Access Statistics for this article
Applied Energy is currently edited by J. Yan
More articles in Applied Energy from Elsevier
Bibliographic data for series maintained by Catherine Liu ().