A comprehensive review of carbon and hydrocarbon assisted water electrolysis for hydrogen production

HyungKuk Ju, Sukhvinder Badwal and Sarbjit Giddey

Applied Energy, 2018, vol. 231, issue C, 502-533

Abstract: Hydrogen is mainly produced by natural gas reforming, which is a highly efficient process with low feedstock costs. However, the rising interest in clean technologies will increase the demand for hydrogen, meaning that other sources will need to be explored. Although coal is currently the major source of power generation, its demand appears to be declining due to the rise in electricity generated from renewable energy sources and the worldwide quest for low-emission power generation. Coal reserves worldwide are abundant, but new technologies would be needed to produce hydrogen from this feedstock. Coal gasification is one well-established technology for this purpose, but it is inefficient and produces high CO2 emissions. An alternative technology that has been investigated over the past few decades is carbon assisted water electrolysis. The basic process is water/steam electrolysis, with part of the energy required for the electrolysis provided by the chemical energy of coal, which reduces the overall electrical energy input. In addition to coal, the process can also use other carbon sources, such as biomass, alcohols or gaseous hydrocarbons. Several studies have investigated this electrochemical route of hydrogen production, employing different electrolytes in a wide temperature range (room temperature to 850 °C) under different process conditions. This paper presents a comprehensive review of carbon assisted water electrolysis, associated materials used and the challenges for the development of the technology at the commercial scale.

Keywords: Electrolyser; Coal; Methanol; Ethanol; Natural gas; Alcohol (search for similar items in EconPapers)
Date: 2018
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (26)

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0306261918314314
Full text for ScienceDirect subscribers only

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:appene:v:231:y:2018:i:c:p:502-533

Ordering information: This journal article can be ordered from
http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/bibliographic
http://www.elsevier. ... 405891/bibliographic

DOI: 10.1016/j.apenergy.2018.09.125

Access Statistics for this article

Applied Energy is currently edited by J. Yan

More articles in Applied Energy from Elsevier
Bibliographic data for series maintained by Catherine Liu ().