Design screening and analysis of gas-fired ammonia-based chemisorption heat pumps for space heating in cold climate

Zhiyao Yang, Ming Qu and Kyle R. Gluesenkamp

Energy, 2020, vol. 207, issue C

Abstract: Thermally-driven ammonia-based chemisorption heat pumps (CSHP) have the potential to provide high-efficiency space heating in cold climates. Using the reversible chemical bond between sorbent salt and ammonia, CSHP thermochemically pumps heat from the cold ambient to the end-uses of space heating at 50 °C. The heating coefficient of performance (COP) of a CSHP is largely dependent on the selection of the sorbent salts, cycle configuration, and the system operation. This study uses a thermodynamic model to investigate the performance of six CSHP system configurations, including four single-effect and two double-effect cycles. The feasibility and performance of 121 available NH3/salt reactions are studied for each configuration. The thermal COP of the cycles and the primary energy COP of the gas-fired CSHP systems are evaluated assuming 50 °C supply temperature for building space heating and the optimal system designs are identified. The highest thermal COP for single-effect and double-effect cycles under −25 °C ambient temperatures are predicted to be 1.22 and 1.57, respectively. The corresponding primary energy COPs are above 1.0 and 1.15, which are 30% higher than condensing furnaces and is sustained into the same cold temperatures.

Keywords: chemisorption; Heat pump; Cold climate; Ammoniate salt; Thermodynamic analysis (search for similar items in EconPapers)
Date: 2020
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Citations: View citations in EconPapers (1)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:207:y:2020:i:c:s0360544220313207

DOI: 10.1016/j.energy.2020.118213

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