Improving inorganic perovskite photovoltaic performance via organic cation addition for efficient solar energy utilization
Dong-Gun Lee,
Padmini Pandey,
Bhaskar Parida,
Jun Ryu,
SungWon Cho,
Jae-Kwang Kim and
Dong-Won Kang
Energy, 2022, vol. 257, issue C
Abstract:
Organic cations help in executing better crystal growth of halide perovskites. Herein, we have realized improved all-inorganic cesium lead halide perovskite film quality with reduced pinholes and high crystallinity in phenylethylammonium (PEA+) assisted perovskite. Additionally, PEA+ cation acts as an additive to control intermediate perovskite phase and executes pure phase perovskite crystal growth as compared to MA+ and FA+ cations assisted perovskite films. X-ray photoelectron and UV–vis spectroscopy results revealed that adding PEA+ in the perovskite helps in almost uniform distribution of Br− ion after post-annealing process. Furthermore, depth profiling analysis reveals that PEA+ in the intermediate phase perovskite interacts more with the ZnO layer beneath perovskite, which helps in the fabrication of compact film. PEA+ sublimates after post-annealing treatment of 300 °C, as no evidence of PEA+ existence was found in characterizations for post-annealed perovskite films. This brings multiple benefits to inorganic mixed halide perovskite film formation. The best performing perovskite solar cell (PSC) exhibits a high conversion efficiency of 14.75% as well as enhanced stability of maintaining almost 83% of its initial efficiency for 400 h. Electrochemical impedance spectroscopy and space-charge-limited current results suggests reduced recombination loss and defect densities in PEA+ assisted PSC.
Keywords: Phenylethylammonium; Inorganic perovskite solar cell; Intermediate phase control; Sublimation (search for similar items in EconPapers)
Date: 2022
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Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:257:y:2022:i:c:s0360544222015432
DOI: 10.1016/j.energy.2022.124640
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