Shale oil redistribution-induced flow regime transition in nanopores

Hai Sun, Tianhao Li, Zheng Li, Dongyan Fan, Lei Zhang, Yongfei Yang, Kai Zhang, Junjie Zhong and Jun Yao

Energy, 2023, vol. 282, issue C

Abstract: The previous neglect of shale oil multi-component characteristics and the nanpore wall properties of real shale result in an insufficient understanding of shale oil flow mechanisms in nanopores. Meanwhile, research on the flow regimes of shale oil remains lacking. In this study, molecular dynamics simulations are employed to investigate the flow of shale oil in hydroxylated quartz nanopores and rough kerogen nanopores. Simulation results show that the flow regime changed as the pressure gradient (∇p) increased to a critical value (∇pc). The velocity profile was parabolic when ∇p < ∇pc, but gradually became piston-like when ∇p ≥ ∇pc. Because increasing ∇p leads the adsorbed molecules desorbing, aggregating in the pore center, and forming clusters that are not easy to shear. Increasing vertical force from pore wall causes fluid aggregation in the pore center as ∇p increases. The ∇pc in kerogen nanopores is larger than that in quartz nanopores due to the rough kerogen surface and sticky layers. Multi-component fluids have higher ∇pc than single-component fluids in quartz nanopores. However, they have the same ∇pc in kerogen nanopores due to the rough kerogen surface. This investigation can provide theoretical basis for high-efficient production of shale oil.

Keywords: Shale oil; Nanopores; Flow regime transition; Pressure gradient; Fluid accumulation; Molecular dynamics simulations (search for similar items in EconPapers)
Date: 2023
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (1)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:282:y:2023:i:c:s0360544223019473

DOI: 10.1016/j.energy.2023.128553

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