Revealing the kinetic behaviors of hydrate formation on bubble surface with different pressure gradients in deep-sea methane seepage areas of the South China Sea

Zhenwu Zhou, Jingchun Feng, Xinyang Zeng, Yan Xie, Bin Wang, Si Zhang, Zhifeng Yang and Yi Wang

Energy, 2024, vol. 308, issue C

Abstract: In the deep-sea methane seepage environment, hydrate formation on the methane bubbles is a crucial pathway for methane transformation, and plays an important role in determining whether seepage methane can enter the surface ocean. While how the pressure determines the hydrate formation process in different water depths remains unclear. In this study, we investigated the formation kinetic characteristics and microstructure evolution of methane hydrate on suspended gas bubbles within varied pressure conditions. The pressure range (4–14 MPa) was in the deep-sea methane seepage environment. The results indicated that pressure obviously affected the hydrate film formation characteristics. As pressure increased, the lateral growth rate of the hydrate film accelerated, the hydrate crystal particles became smaller, and the initial hydrate film surface became smoother. Raman spectroscopy results showed that pressure changes did not obviously alter the microporous evolution on the hydrate film surface, that the gas-phase/water-phase Raman peak area ratio exhibited similar trends. The dissolved methane concentration under different pressure conditions was not the primary factor affecting hydrate thickening, rather, it depended mainly on the driving force. This study is of great significance in revealing the characteristics of methane hydrate formation and methane transfer in the oceanic methane seepage environment.

Keywords: Deep-sea methane seepage; Hydrate film; Pressure gradient; Growth kinetics; Suspended bubble (search for similar items in EconPapers)
Date: 2024
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Persistent link: https://EconPapers.repec.org/RePEc:eee:energy:v:308:y:2024:i:c:s0360544224025829

DOI: 10.1016/j.energy.2024.132808

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