Statistical mechanical model with chemical reaction

J.S. HØye and K. Olaussen

Physica A: Statistical Mechanics and its Applications, 1980, vol. 104, issue 3, 435-446

Abstract: We study a mixture of classical particles where unequal particles interact with strong binding forces, while equal particles repel each other with a hard-core interaction. The interactions are constructed so that at most two unequal particles can bind to a molecule. Such a system can be interpreted as one where the basic species react to form diatomic molecules, the equilibrium of which at low densities is governed by the well-known law of mass action. Our results explicate and supplement the approach of Andersen to this problem.

Date: 1980
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:104:y:1980:i:3:p:435-446

DOI: 10.1016/0378-4371(80)90006-0

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