Directed random walk in adsorbed monolayer

O. Bénichou, A.M. Cazabat, M. Moreau and G. Oshanin

Physica A: Statistical Mechanics and its Applications, 1999, vol. 272, issue 1, 56-86

Abstract: We study the dynamics of a tracer particle, which performs a totally directed random walk in an adsorbed monolayer composed of mobile hard-core particles undergoing continuous exchanges with a vapour phase. In terms of a mean-field-type approach, based on the decoupling of the tracer–particle–particle correlation functions into the product of pairwise, tracer–particle correlations, we determine the density profiles of the monolayer particles, as seen from the stationary moving tracer, and calculate its terminal velocity, Vtr. In the general case the latter is determined implicitly, as the solution of a certain transcendental equation. In two extreme limits of slow and fast monolayer particles diffusion, we obtain explicit asymptotic forms of Vtr. We show next that the density profile in the monolayer is strongly inhomogeneous: in front of the stationary moving tracer the local density is higher than the average value, ρL, and approaches ρL as an exponential function of the distance from the tracer; past the tracer the local density is lower than ρL and the approach to ρL may proceed differently depending on whether the particle number in the monolayer is explicitly conserved or not. In the former case the approach is described by an exponential dependence with a different characteristic length, compared with the behaviour in front of the tracer; in the latter case, the density tends to ρL algebraically. The characteristic lengths and the amplitudes of the density relaxation functions are also determined explicitly.

Keywords: Hard-core lattice gas; Langmuir adsorption/desorption model; Biased tracer diffusion (search for similar items in EconPapers)
Date: 1999
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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:272:y:1999:i:1:p:56-86

DOI: 10.1016/S0378-4371(99)00251-4

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