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A mathematical theorem as the basis for the second law: Thomson's formulation applied to equilibrium

A.E. Allahverdyan and Th.M. Nieuwenhuizen

Physica A: Statistical Mechanics and its Applications, 2002, vol. 305, issue 3, 542-552

Abstract: There are several formulations of the second law, and they may, in principle, have different domains of validity. Here a simple mathematical theorem is proven which serves as the most general basis for the second law, namely the Thomson formulation (“cyclic changes cost energy”), applied to equilibrium. This formulation of the second law is a property akin to particle conservation (normalization of the wave function). It has been strictly proven for a canonical ensemble, and made plausible for a micro-canonical ensemble.

Keywords: Second law; Thomson formulation; Mathematical proof; Perpetual motion; Persistent currents (search for similar items in EconPapers)
Date: 2002
References: View complete reference list from CitEc
Citations: View citations in EconPapers (1)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:phsmap:v:305:y:2002:i:3:p:542-552

DOI: 10.1016/S0378-4371(01)00605-7

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