Development of granular thermochemical heat storage composite based on calcium oxide

B.Q. Xia, C.Y. Zhao, J. Yan and A.A. Khosa

Renewable Energy, 2020, vol. 147, issue P1, 969-978

Abstract: Thermochemical heat storage is a promising technology for the efficient utilization of renewable energy. Among available thermochemical systems, the CaO/Ca(OH)2 system is the most popular because of availability and cost. However, poor powder properties and low heat storage rates hinder the successful implementation of this system. This study presented a novel synthetic method of granular composites based on carboxymethyl cellulose sodium (CMC) and vermiculite in order to mitigate the drawbacks of natural materials and stabilize the size of materials for use in moving bed reactors. TGA and DSC experiments and some essential characterizations were done in order to evaluate the improvements on the basis of three objectives: the heat storage rate, heat storage density, and mechanical properties, compared with natural materials. Results showed that the granular composite still had great structural integrity after several dehydration/hydration cycles, whereas compacted natural materials had fragmented. Additionally, composite had a higher heat storage rate than natural materials. The gravimetric storage density of granular composite was slightly reduced while the volumetric storage density was enhanced up to approximately 124% as compared to the powdery Ca(OH)2 material. It was concluded that present synthetic method is a promising route for the development of Ca-based composite materials.

Keywords: Thermochemical heat storage; Granular composite; Heat storage density; Heat storage rate; Mechanical property (search for similar items in EconPapers)
Date: 2020
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (7)

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0960148119313953
Full text for ScienceDirect subscribers only

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:renene:v:147:y:2020:i:p1:p:969-978

DOI: 10.1016/j.renene.2019.09.065

Access Statistics for this article

Renewable Energy is currently edited by Soteris A. Kalogirou and Paul Christodoulides

More articles in Renewable Energy from Elsevier
Bibliographic data for series maintained by Catherine Liu ().