Effect of thermochemically fractionation before hydrothermal liquefaction of herbaceous biomass on biocrude characteristics

Seong Ju Kim and Byung Hwan Um

Renewable Energy, 2020, vol. 160, issue C, 612-622

Abstract: Hydrothermal liquefaction (HTL) of fractionated two types herbaceous biomass (kenaf and miscanthus) by dilute acid, organosolv, alkaline, or demineralization process was carried out under ethanol water co-solvent at 350 °C for 30 min to examine the biocrude yield and characteristics. The biocrude properties were comprehensively characterized by HPLC, elemental, GC-MS, and TGA analysis. Fractionation technologies before HTL effectively increased biocrude yield up to 38% compared to that of untreated herbaceous biomass (31%), except for organosolv fractionation of miscanthus, especially, HTL after alkaline fractionation showed high yield and energy recovery ratio up to 70%. Elemental analysis showed that HHV of biocrude was negatively affected by hydrolysis reaction of high lignin content after dilute acid fractionation. The GC-MS analysis revealed that carbohydrates-derived compound significantly increased in the biocrude obtained after organosolv and alkaline fractionation due to holocellulose increases through fractionation process. Additionally, TGA results indicated that the ratio of high-boiling-point compounds in biocrude obtained after demineralization was expanded compared with untreated due to ash removal, which could act as a catalyst.

Keywords: Hydrothermal liquefaction; Herbaceous biomass; Fractionation; Biocrude; Solid residue (search for similar items in EconPapers)
Date: 2020
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Citations: View citations in EconPapers (6)

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Persistent link: https://EconPapers.repec.org/RePEc:eee:renene:v:160:y:2020:i:c:p:612-622

DOI: 10.1016/j.renene.2020.07.002

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