Microwave catalytic co-pyrolysis of microalgae and high density polyethylene over activated carbon supported bimetallic: Characteristics and bio-oil analysis

Dianzhao Fan, Ronglin Yang, Chunxiang Chen, Song Qiu, Shiyuan He and Haosen Shi

Renewable Energy, 2024, vol. 235, issue C

Abstract: Three activated carbon (AC) supported bimetallic catalysts (Ce-Fe/AC, Ce-Ni/AC, Ce-Cu/AC) were prepared, and the catalysts' impacts on the microwave co-pyrolysis of Chlorella vulgaris (C. vulgaris) and high density polyethylene (HDPE) (mixing ratio of 1:1, C1HP1) were explored. The findings indicated that the catalysts promoted the co-pyrolysis of C1HP1 substantially at 40 % and 50 % additions. The minimum reaction time (2945 s) was observed at 40 % Ce–Fe/AC. Compared to the C1HP1 group, Ce-Fe/AC groups exhibited a pronounced promotional impact on bio-oil production, with the maximum bio-oil yield (25.8 %) catalyzed by 30 % Ce–Fe/AC. Furthermore, the catalyst's high hydrogenation activity and deoxygenation promoted the formation of H2O, NH3 and HCN, achieving over 40 % efficiencies in deoxygenation and denitrification for bio-oil. 40 % Ce–Cu/AC exhibited superior performance with the highest hydrocarbon (67.43 %) and aromatic hydrocarbon content (50.75 %), as well as leading deoxygenation (44.38 %) and nitrogen removal (58.63 %) efficiency among the AC supported bimetallic catalysts.

Keywords: High density polyethylene; Chlorella vulgaris; Activated carbon supported catalysts; Microwave co-pyrolysis; Bio-oil (search for similar items in EconPapers)
Date: 2024
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Persistent link: https://EconPapers.repec.org/RePEc:eee:renene:v:235:y:2024:i:c:s0960148124013910

DOI: 10.1016/j.renene.2024.121323

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