A comparative study of KOH/Al2O3 and KOH/NaY catalysts for biodiesel production via transesterification from palm oil
Krisada Noiroj,
Pisitpong Intarapong,
Apanee Luengnaruemitchai and
Samai Jai-In
Renewable Energy, 2009, vol. 34, issue 4, 1145-1150
Abstract:
The transesterification of palm oil to methyl esters (biodiesel) was studied using KOH loaded on Al2O3 and NaY zeolite supports as heterogeneous catalysts. Reaction parameters such as reaction time, wt% KOH loading, molar ratio of oil to methanol, and amount of catalyst were optimized for the production of biodiesel. The 25wt% KOH/Al2O3 and 10wt% KOH/NaY catalysts are suggested here to be the best formula due to their biodiesel yield of 91.07% at temperatures below 70°C within 2–3h at a 1:15 molar ratio of palm oil to methanol and a catalyst amount of 3–6wt%. The leaching of potassium species in both spent catalysts was observed. The amount of leached potassium species of the KOH/Al2O3 was somewhat higher compared to that of the KOH/NaY catalyst. The prepared catalysts were characterized by using several techniques such as XRD, BET, TPD, and XRF.
Keywords: Transesterification; Biodiesel; Al2O3; NaY; Solid base catalyst; Leaching (search for similar items in EconPapers)
Date: 2009
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Citations: View citations in EconPapers (20)
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Persistent link: https://EconPapers.repec.org/RePEc:eee:renene:v:34:y:2009:i:4:p:1145-1150
DOI: 10.1016/j.renene.2008.06.015
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