Biodiesel with low temperature properties: Enzymatic synthesis of fusel alcohol fatty acid ester in a solvent free system
Meng Wang,
Kaili Nie,
Feng Yun,
Hao Cao,
Li Deng,
Fang Wang and
Tianwei Tan
Renewable Energy, 2015, vol. 83, issue C, 1020-1025
Abstract:
Poor low temperature behavior, the critical defect of biodiesel, limits its utilization in cold districts. This research provided a new biodiesel production process by enzymatic synthesis using fusel alcohol and fatty acid esters in a solvent free system with a significant effect on the improvement of biodiesel's low temperature performance. The optimal conditions for the enzymatic reaction of fusel alcohol and waste cooking oil (WCO) esters were established: immobilized lipase 14% (w/w), total water content 5% (w/w), 40 °C, three-times feeding daily, shaking speed 200 rpm. The ester yield reached 90.4% under optimal conditions. The cold filter plugging point (CFPP) of the fusel alcohol esters was −11 °C, 16 °C lower than the methyl esters of the WCO. The green enzymatic synthesis process and the CFPP results were examined in this research.
Keywords: Biodiesel; Candida sp. 99–125 lipase; Fusel alcohol; Solvent-free system; Cold filter plugging point (search for similar items in EconPapers)
Date: 2015
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Citations: View citations in EconPapers (13)
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Persistent link: https://EconPapers.repec.org/RePEc:eee:renene:v:83:y:2015:i:c:p:1020-1025
DOI: 10.1016/j.renene.2015.05.058
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