Precise Measurements of the Temperature-Frequency Dependence of the Conductivity of Cellulose—Insulating Oil—Water Nanoparticles Composite

Pawel Zukowski, Przemyslaw Rogalski, Tomasz N. Koltunowicz, Konrad Kierczynski and Vitalii Bondariev
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Pawel Zukowski: Department of Electrical Devices and High Voltage Technology, Lublin University of Technology, 20-618 Lublin, Poland
Przemyslaw Rogalski: Department of Electrical Devices and High Voltage Technology, Lublin University of Technology, 20-618 Lublin, Poland
Tomasz N. Koltunowicz: Department of Electrical Devices and High Voltage Technology, Lublin University of Technology, 20-618 Lublin, Poland
Konrad Kierczynski: Department of Electrical Devices and High Voltage Technology, Lublin University of Technology, 20-618 Lublin, Poland
Vitalii Bondariev: Department of Electrical Devices and High Voltage Technology, Lublin University of Technology, 20-618 Lublin, Poland

Energies, 2020, vol. 14, issue 1, 1-26

Abstract: This article presents direct σDC and alternating σ(f) current conductivity measurements obtained by the frequency domain spectroscopy (FDS) method on cellulose-transformer oil–water nanoparticle composite with a moisture content of (5.0 ± 0.2)% by weight in a temperature range from 293.15 to 333.15 K with step of 8 K. The uncertainty of temperature maintenance during measurements was below ±0.01 K. The sample was prepared for testing in a manner as close as possible to the cellulose insulation moisturizing process in power transformers. For the analysis of the results obtained, a model of alternating and direct current hopping conductivity was used, based on the quantum phenomenon of electron tunneling between the potential wells and nanodrops of water. It was observed that on the d(logσ)/d(logf)-derived waveforms there was a clear low-frequency maximum, and a tendency to reach the next maximum in the high-frequency area was visible. On this basis it was established that the increase in conductivity takes place in two stages. It was found that the position of σ(f) waveforms in the double logarithmic coordinates is influenced by the temperature dependence both of the conductivity and of the relaxation time of the conductivity. These relationships are described with the appropriate activation energies of the conductivity and relaxation time of conductivity. Based on the analysis of experimental data using Arrhenius diagrams, average values of the activation energy of conductivity ΔWσ ≈ (0.894 ± 0.0134) eV and the relaxation time of conductivity ΔWτσ ≈ (0.869 ± 0.0107) eV were determined. The values were equal within the limits of uncertainty and their mean value was ΔW ≈ (0.881 ± 0.0140) eV. Using the mean value of the activation energy, the frequency dependence of conductivity, obtained at different temperatures, was shifted to 293.15 K. For this purpose, first the waveforms were shifted along the horizontal and then the vertical axis. It was found that after the shift the σ(f) waveforms for the different temperatures overlap perfectly. This means that the shape of the frequency dependence of the conductivity is determined by the moisture content of the pressboard. The position of the waveforms in relation to the coordinates is determined by the temperature relationships of the conductivity and the relaxation time of the conductivity.

Keywords: power transformer; pressboard; mineral oil; moisture; conductivity; activation energy (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2020
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (1)

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