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Principle and Feasibility Study of Proposed Hydrate-Based Cyclopentane Purification Technology

Xianbing Hu, Lingjie Sun, Chengyang Yuan, Man Li, Hongsheng Dong, Lunxiang Zhang (), Lei Yang, Jiafei Zhao and Yongchen Song ()
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Xianbing Hu: Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy & Power Engineering, Dalian University of Technology, Dalian 116024, China
Lingjie Sun: Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy & Power Engineering, Dalian University of Technology, Dalian 116024, China
Chengyang Yuan: Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy & Power Engineering, Dalian University of Technology, Dalian 116024, China
Man Li: Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy & Power Engineering, Dalian University of Technology, Dalian 116024, China
Hongsheng Dong: Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy & Power Engineering, Dalian University of Technology, Dalian 116024, China
Lunxiang Zhang: Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy & Power Engineering, Dalian University of Technology, Dalian 116024, China
Lei Yang: Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy & Power Engineering, Dalian University of Technology, Dalian 116024, China
Jiafei Zhao: Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy & Power Engineering, Dalian University of Technology, Dalian 116024, China
Yongchen Song: Key Laboratory of Ocean Energy Utilization and Energy Conservation of Ministry of Education, School of Energy & Power Engineering, Dalian University of Technology, Dalian 116024, China

Energies, 2023, vol. 16, issue 12, 1-10

Abstract: The separation of azeotropic mixtures has conventionally been one of the most challenging tasks in industrial processes due to the fact that components in the mixture will undergo gas–liquid phase transition at the same time. We proposed a method for separating azeotropes using hydrate formation as a solid–liquid phase transition. The feasibility of hydrate-based separation is determined by analyzing the crystal structure and chemical bonds of hydrate. Taking the azeotrope cyclopentane and neohexane in petroleum as an example, cyclopentane (95%) was purified to 98.56% yield using the proposed hydrate-based cyclopentane purification technology. However, this is difficult to achieve using conventional distillation methods. The proposed method is simple in operation and yields a good separation effect. This study provides a new method for separating cyclopentane and neohexane.

Keywords: azeotrope; cyclopentane; neohexane; hydrate; phase transition (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2023
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