Influence of Thermochemical Conversion Technologies on Biochar Characteristics from Extensive Grassland for Safe Soil Application

Thomas Heinrich (), Korbinian Kaetzl, Judy A. Libra and Thomas Hoffmann
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Thomas Heinrich: Department of Postharvest Technologies, Leibniz Institute for Agricultural Engineering and Bioeconomy, Max-Eyth-Allee 100, 14469 Potsdam, Germany
Korbinian Kaetzl: Section of Grassland Science and Renewable Plant Resources, Faculty of Organic Agricultural Sciences, University of Kassel, Steinstr. 19, 37213 Witzenhausen, Germany
Judy A. Libra: Department of Postharvest Technologies, Leibniz Institute for Agricultural Engineering and Bioeconomy, Max-Eyth-Allee 100, 14469 Potsdam, Germany
Thomas Hoffmann: Department of Postharvest Technologies, Leibniz Institute for Agricultural Engineering and Bioeconomy, Max-Eyth-Allee 100, 14469 Potsdam, Germany

Energies, 2023, vol. 16, issue 4, 1-18

Abstract: Grass and other herbaceous biomass are abundant, but often under- or not utilized as a renewable resource. Here, the production of biochar from extensive late-harvest grass via multiple thermochemical conversion technologies was investigated at lab and farm scale for use in soil applications. While biochar is a product with highly diverse potential applications, it has a multitude of benefits for agricultural usage as a soil amendment, if the quality adheres to certain limit values of potentially toxic constituents. The results show that the biochar can adhere to all limit values of the European Biochar Certificate (EBC) for utilization in agriculture. Generally, the contents of heavy metals were well below the proposed EBC limits and very low PAH concentrations in the biochar were achieved. The high ash content in the grass of 7.71 wt% db resulted in high nutrient concentrations in the biochar, of benefit in soil applications, but the ash also contains chlorine, nitrogen and sulphur, which presents a challenge for the operation of the thermochemical processes themselves due to corrosion and emission limits. In the farm-scale processes, ash retention ranged from 53.7 wt% db for an autothermal batch process, reaching up to 93.7 wt% db for a batch allothermal process. The release of Cl, N and S was found to differ substantially between processes. Retention ranged from 41.7%, 22.9% and 27.6%, respectively, in a continuous allothermal farm-scale pyrolysis process, to 71.7%, 49.7% and 73.9%, with controlled lab-scale pyrolysis at 450 °C, demonstrating that process optimization may be possible.

Keywords: grass; biochar; pyrolysis; hydrothermal carbonization; ash; biomass (search for similar items in EconPapers)
JEL-codes: Q Q0 Q4 Q40 Q41 Q42 Q43 Q47 Q48 Q49 (search for similar items in EconPapers)
Date: 2023
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