Does Acid Addition Improve Liquid Hot Water Pretreatment of Lignocellulosic Biomass towards Biohydrogen and Biogas Production?

George Dimitrellos, Gerasimos Lyberatos and Georgia Antonopoulou
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George Dimitrellos: Institute of Chemical Engineering Sciences, Stadiou, Platani, GR 26504 Patras, Greece
Gerasimos Lyberatos: Institute of Chemical Engineering Sciences, Stadiou, Platani, GR 26504 Patras, Greece
Georgia Antonopoulou: Institute of Chemical Engineering Sciences, Stadiou, Platani, GR 26504 Patras, Greece

Sustainability, 2020, vol. 12, issue 21, 1-14

Abstract: The effect of liquid hot water (LHW) pretreatment with or without acid addition (A-LHW) on the production of hydrogen—through dark fermentation (DF)—and methane—through anaerobic digestion (AD)—using three different lignocellulosic biomass types (sunflower straw (SS), grass lawn (GL), and poplar sawdust (PS)) was investigated. Both pretreatment methods led to hemicellulose degradation, but A-LHW resulted in the release of more potential inhibitors (furans and acids) than the LHW pretreatment. Biological hydrogen production (BHP) of the cellulose-rich solid fractions obtained after LHW and A-LHW pretreatment was enhanced compared to the untreated substrates. Due to the release of inhibitory compounds, LHW pretreatment led to higher biochemical methane potential (BMP) than A-LHW pretreatment when both separated fractions (liquid and solid) obtained after pretreatments were used for AD. The recovered energy in the form of methane with LHW pretreatment was 8.4, 12.5, and 7.5 MJ/kg total solids (TS) for SS, GL, and PS, respectively.

Keywords: liquid hot water pretreatment; acid; hydrothermal; hydrogen; methane; anaerobic digestion; lignocellulosic biomass (search for similar items in EconPapers)
JEL-codes: O13 Q Q0 Q2 Q3 Q5 Q56 (search for similar items in EconPapers)
Date: 2020
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (5)

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