Abnormal thermally-stimulated dynamic organic phosphorescence
He Wang,
Huili Ma,
Nan Gan,
Kai Qin,
Zhicheng Song,
Anqi Lv,
Kai Wang,
Wenpeng Ye,
Xiaokang Yao,
Chifeng Zhou,
Xiao Wang,
Zixing Zhou,
Shilin Yang,
Lirong Yang,
Cuimei Bo,
Huifang Shi,
Fengwei Huo,
Gongqiang Li (),
Wei Huang () and
Zhongfu An ()
Additional contact information
He Wang: Nanjing Tech University
Huili Ma: Nanjing Tech University
Nan Gan: Northwestern Polytechnical University
Kai Qin: Nanjing Tech University
Zhicheng Song: Nanjing Tech University
Anqi Lv: Nanjing Tech University
Kai Wang: Nanjing Tech University
Wenpeng Ye: Nanjing Tech University
Xiaokang Yao: Nanjing Tech University
Chifeng Zhou: Nanjing Tech University
Xiao Wang: Xiamen University
Zixing Zhou: Nanjing Tech University
Shilin Yang: Nanjing Tech University
Lirong Yang: Nanjing Tech University
Cuimei Bo: Nanjing Tech University
Huifang Shi: Nanjing Tech University
Fengwei Huo: Nanjing Tech University
Gongqiang Li: Nanjing Tech University
Wei Huang: Nanjing Tech University
Zhongfu An: Nanjing Tech University
Nature Communications, 2024, vol. 15, issue 1, 1-8
Abstract:
Abstract Dynamic luminescence behavior by external stimuli, such as light, thermal field, electricity, mechanical force, etc., endows the materials with great promise in optoelectronic applications. Upon thermal stimulus, the emission is inevitably quenched due to intensive non-radiative transition, especially for phosphorescence at high temperature. Herein, we report an abnormal thermally-stimulated phosphorescence behavior in a series of organic phosphors. As temperature changes from 198 to 343 K, the phosphorescence at around 479 nm gradually enhances for the model phosphor, of which the phosphorescent colors are tuned from yellow to cyan-blue. Furthermore, we demonstrate the potential applications of such dynamic emission for smart dyes and colorful afterglow displays. Our results would initiate the exploration of dynamic high-temperature phosphorescence for applications in smart optoelectronics. This finding not only contributes to an in-depth understanding of the thermally-stimulated phosphorescence, but also paves the way toward the development of smart materials for applications in optoelectronics.
Date: 2024
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DOI: 10.1038/s41467-024-45811-0
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