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Float-stacked graphene–PMMA laminate

Seung-Il Kim, Ji-Yun Moon, Seok-Ki Hyeong, Soheil Ghods, Jin-Su Kim, Jun-Hui Choi, Dong Seop Park, Sukang Bae, Sung Ho Cho (), Seoung-Ki Lee () and Jae-Hyun Lee ()
Additional contact information
Seung-Il Kim: Ajou University
Ji-Yun Moon: Ajou University
Seok-Ki Hyeong: Ajou University
Soheil Ghods: Ajou University
Jin-Su Kim: Ajou University
Jun-Hui Choi: Ajou University
Dong Seop Park: Ajou University
Sukang Bae: Institute of Advanced Composite Materials, Korea Institute of Science and Technology
Sung Ho Cho: Samsung Display
Seoung-Ki Lee: Pusan National University
Jae-Hyun Lee: Ajou University

Nature Communications, 2024, vol. 15, issue 1, 1-8

Abstract: Abstract Semi-infinite single-atom-thick graphene is an ideal reinforcing material that can simultaneously improve the mechanical, electrical, and thermal properties of matrix. Here, we present a float-stacking strategy to accurately align the monolayer graphene reinforcement in polymer matrix. We float graphene-poly(methylmethacrylate) (PMMA) membrane (GPM) at the water–air interface, and wind-up layer-by-layer by roller. During the stacking process, the inherent water meniscus continuously induces web tension of the GPM, suppressing wrinkle and folding generation. Moreover, rolling-up and hot-rolling mill process above the glass transition temperature of PMMA induces conformal contact between each layer. This allows for pre-tension of the composite, maximizing its reinforcing efficiency. The number and spacing of the embedded graphene fillers are precisely controlled. Notably, we accurately align 100 layers of monolayer graphene in a PMMA matrix with the same intervals to achieve a specific strength of about 118.5 MPa g−1 cm3, which is higher than that of lightweight Al alloy, and a thermal conductivity of about 4.00 W m−1 K−1, which is increased by about 2,000 %, compared to the PMMA film.

Date: 2024
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DOI: 10.1038/s41467-024-46502-6

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