An Overview of Biodiesel Production via Heterogeneous Catalysts: Synthesis, Current Advances, and Challenges

Maya Yaghi, Sandra Chidiac, Sary Awad, Youssef El Rayess () and Nancy Zgheib ()
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Maya Yaghi: Department of Chemical Engineering, School of Engineering, Holy Spirit University of Kaslik, Jounieh BP 446, Lebanon
Sandra Chidiac: Department of Agriculture and Food Engineering, School of Engineering, Holy Spirit University of Kaslik, Jounieh BP 446, Lebanon
Sary Awad: IMT-Atlantique, GEPEA UMR-CNRS 6144, 44300 Nantes, France
Youssef El Rayess: Department of Agriculture and Food Engineering, School of Engineering, Holy Spirit University of Kaslik, Jounieh BP 446, Lebanon
Nancy Zgheib: Department of Chemical Engineering, School of Engineering, Holy Spirit University of Kaslik, Jounieh BP 446, Lebanon

Clean Technol., 2025, vol. 7, issue 3, 1-55

Abstract: Biodiesel, a renewable and environmentally friendly alternative to fossil fuels, has attracted significant attention due to its potential to reduce greenhouse gas emissions. However, high production costs and complex processing remain challenges. Heterogeneous catalysts have shown promise in overcoming these barriers by offering benefits, such as easy separation, reusability, low-cost raw materials, and the ability to reduce reaction times and energy consumption. This review evaluates key classes of heterogeneous catalysts, such as metal oxides, ion exchange resins, and zeolites, and their performance in transesterification and esterification processes. It highlights the importance of catalyst preparation methods, textural properties, including surface area, pore volume, and pore size, activation techniques, and critical operational parameters, like the methanol-to-oil ratio, temperature, time, catalyst loading, and reusability. The analysis reveals that catalysts supported on high surface area materials often achieve higher biodiesel yields, while metal oxides derived from natural sources provide cost-effective and sustainable options. Challenges, such as catalyst deactivation, sensitivity to feedstock composition, and variability in performance, are discussed. Overall, the findings underscore the potential of heterogeneous catalysts to enhance biodiesel production efficiency, although further optimization and standardized evaluation protocols are necessary for their broader industrial application.

Keywords: biodiesel; heterogeneous base catalyst; heterogeneous acid catalysts; alkaline metal earth oxides; zeolites; heteropoly acid (search for similar items in EconPapers)
JEL-codes: Q2 Q3 Q4 Q5 (search for similar items in EconPapers)
Date: 2025
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