Biochars and Engineered Biochars for Water and Soil Remediation: A Review

Tariqul Islam, Yanliang Li and Hefa Cheng
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Tariqul Islam: School of Environment and Civil Engineering, Dongguan University of Technology, Dongguan 523808, China
Yanliang Li: School of Environment and Civil Engineering, Dongguan University of Technology, Dongguan 523808, China
Hefa Cheng: College of Urban and Environmental Sciences, Peking University, Beijing 100871, China

Sustainability, 2021, vol. 13, issue 17, 1-25

Abstract: Biochars (BCs) are considered as ecofriendly and multifunctional materials with significant potential for remediation of contaminated water and soils, while engineered biochars (E-BCs) with enlarged surface areas and abundant surface functional groups can perform even better in environmental remediation. This review systematically summarizes the key physical and chemical properties of BCs that affect their pollutant sorption capacities, major methods employed for modification of E-BCs, the performance of BCs/E-BCs in removing major types of organic (e.g., antibiotics and pesticides) and inorganic pollutants (e.g., heavy metals), and the corresponding removal mechanisms. The physical and chemical properties of BCs—such as ash or mineral contents, aromaticity, surface structures, pH, and surface functional groups (e.g., C=O, -COOH, -OH, and -NH 2 )—depend primarily on their feedstock sources (i.e., plant, sludge, or fecal) and the pyrolysis temperature. Ion exchange, precipitation, electrostatic attraction, and complexation are the main mechanisms involved in the adsorption of inorganic pollutants on BCs/E-BCs, whereas hydrogen bonding, pore filling, electrostatic attraction, hydrophobic interaction, and van der Waals forces are the major driving forces for the uptake of organic pollutants. Despite their significant promises, more pilot and field scale investigations are necessary to demonstrate the practical applicability and viability of BCs/E-BCs in water and soil remediation.

Keywords: porous carbonaceous material; environmental remediation; adsorption; aromaticity; alkalinity; surface functional group (search for similar items in EconPapers)
JEL-codes: O13 Q Q0 Q2 Q3 Q5 Q56 (search for similar items in EconPapers)
Date: 2021
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (2)

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