Study on Rates of NH 3 Adsorption and Desorption in SCR on Various Engine Operation Conditions

Hyun Jo, Ahyun Ko, Jinyoung Jang and Ocktaeck Lim ()
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Hyun Jo: Graduate School of Mechanical Engineering, University of Ulsan, Ulsan 44610, Republic of Korea
Ahyun Ko: Korea Institute of Energy Research, Daejeon 34129, Republic of Korea
Jinyoung Jang: Korea Institute of Energy Research, Daejeon 34129, Republic of Korea
Ocktaeck Lim: Graduate School of Mechanical Engineering, University of Ulsan, Ulsan 44610, Republic of Korea

Sustainability, 2023, vol. 15, issue 19, 1-16

Abstract: Aging diesel engines on the road require the development of an after-treatment system to meet current emission regulations, and a reduction in NOx (Nitrogen Oxide) is significant. The SCR (Selective Catalytic Reduction) system is the after-treatment system for removing NOx from exhaust gas in diesel engines using NH 3 (Ammonia) gas. However, the mixing and conversion process between NH 3 and NOx in SCR has not been entirely clarified. That process produces NH 3 slip in the catalyst surface; the NH 3 slip will make the after-treatment performance worse. This study informs how the UWS (Urea Water Solution) injection controlling method can minimize the NH 3 slip in the after-treatment system. For this, the NH 3 adsorption and desorption rates are important factors for determining the quantity of UWS injection in the system. The NH 3 adsorption rate and desorption rate in the SCR are not significantly affected by engine speed, i.e., the exhaust gas flow rate. However, as the exhaust gas temperature increased, the adsorption rate and desorption rate of NH 3 in the SCR increased. Through this, the exhaust gas temperature dramatically affects the NH 3 adsorption rate and desorption rate in the SCR. Therefore, if the urea water is injected based on this knowledge that the NH 3 adsorption amount in the SCR decreases as the exhaust gas flow rate increases, NH 3 slip can be suppressed and a high NOx reduction rate can be achieved. Therefore, if the SCR adsorption and desorption mechanisms are analyzed according to the exhaust temperature and the exhaust flow rate in this paper, it can be used as a reference for selecting an appropriate SCR when retrofitting an old diesel engine car.

Keywords: urea-SCR; diesel engine; NH 3 adsorption; NH 3 slip; nitrogen oxides (NOx) (search for similar items in EconPapers)
JEL-codes: O13 Q Q0 Q2 Q3 Q5 Q56 (search for similar items in EconPapers)
Date: 2023
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