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Ethylene Recovery via Pebax-Based Composite Membrane: Numerical Optimization

Nadia Hartini Suhaimi, Norwahyu Jusoh (), Syafeeqa Syaza Rashidi, Christine Wei Mann Ch’ng and Nonni Soraya Sambudi
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Nadia Hartini Suhaimi: Department of Chemical Engineering, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia
Norwahyu Jusoh: Department of Chemical Engineering, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia
Syafeeqa Syaza Rashidi: Department of Chemical Engineering, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia
Christine Wei Mann Ch’ng: Department of Chemical Engineering, Universiti Teknologi PETRONAS, Seri Iskandar 32610, Malaysia
Nonni Soraya Sambudi: Chemical Engineering Study, Universitas Pertamina, Jl. Teuku Nyak Arief, RT.7/RW.8, Simprug, Kec. Kby. Lama, Kota Jakarta Selatan, Daerah Khusus Ibukota Jakarta 12220, Indonesia

Sustainability, 2023, vol. 15, issue 3, 1-14

Abstract: Membrane technology, particularly polymeric membranes, is utilized in major industrial ethylene recovery owing to the very convenient and robust process. Thus, in this paper, a composite membrane (CM) comprising SAPO-34 and Pebax-1657 was employed to conduct a separation performance under two operating conditions, including temperatures and pressures, ranging from 25.0–60.0 °C and 3.5–10.0 bar, respectively. CO 2 permeability and CO 2 /C 2 H 4 ideal selectivity values that ranged from 105.68 to 262.86 Barrer and 1.81 to 3.52, respectively, were obtained via the experimental works. The separation of carbon dioxide (CO 2 ) from ethylene (C 2 H 4 ) has then been optimized using response surface methodology (RSM) by adopting a central composite design (CCD) method. As a result, the ideal operational conditions were discovered at a temperature of 60.0 °C and pressure of 10.0 bar with the maximum CO 2 permeability of 233.62 Barrer and CO 2 /C 2 H 4 ideal selectivity of 3.22. The typical discrepancies between experimental and anticipated data for CO 2 permeability and CO 2 /C 2 H 4 ideal selectivity were 1.67% and 3.10%, respectively, demonstrating the models’ validity. Overall, a new combination of Pebax-1657 and SAPO-34 composite membrane could inspire the latest understanding of the ethylene recovery process.

Keywords: CO 2 /C 2 H 4 separation; composite membrane; optimization; response surface methodology (search for similar items in EconPapers)
JEL-codes: O13 Q Q0 Q2 Q3 Q5 Q56 (search for similar items in EconPapers)
Date: 2023
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