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Development of Sustainable Magnetic Biosorbent Using Aqueous Leaf Extract of Vallesia glabra for Methylene Blue Removal from Wastewater

Luis Medina-Zazueta, F. C. Miranda-Castro, F. Romo-Garcia, M. Martínez-Gil, H. E. Esparza-Ponce, D. Encinas-Basurto and Jaime Ibarra ()
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Luis Medina-Zazueta: Posgrado en Nanotecnología, Departamento de Física, Universidad de Sonora, Unidad Regional Centro, Hermosillo 83000, Sonora, Mexico
F. C. Miranda-Castro: Posgrado en Nanotecnología, Departamento de Física, Universidad de Sonora, Unidad Regional Centro, Hermosillo 83000, Sonora, Mexico
F. Romo-Garcia: Departamento de Física, Matemáticas e Ingeniería, Universidad de Sonora, Unidad Regional Sur, Navojoa 85880, Sonora, Mexico
M. Martínez-Gil: Departamento de Física, Matemáticas e Ingeniería, Universidad de Sonora, Unidad Regional Sur, Navojoa 85880, Sonora, Mexico
H. E. Esparza-Ponce: Centro de Investigación en Materiales Avanzados, Complejo Industrial Chihuahua, Chihuahua 31136, Chihuahua, Mexico
D. Encinas-Basurto: Departamento de Física, Matemáticas e Ingeniería, Universidad de Sonora, Unidad Regional Sur, Navojoa 85880, Sonora, Mexico
Jaime Ibarra: Departamento de Física, Matemáticas e Ingeniería, Universidad de Sonora, Unidad Regional Sur, Navojoa 85880, Sonora, Mexico

Sustainability, 2023, vol. 15, issue 5, 1-18

Abstract: Vallesia glabra ( Vg ) is a species that has been used in traditional medicine due to its secondary metabolites (alkaloids, saponins, flavonoids, phenols, and cardiac glucosides) for the treatment of measles, rheumatism, muscle aches, and eye inflammation. The biosynthesis of magnetite nanoparticles (Fe 3 O 4 NPs) was carried out using an aqueous leaf extract of Vg and was characterized using Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS). Afterward, the magnetic adsorbent was tested for its potential to remove cationic dye from aqueous solutions at different pH and adsorbent mass and its reusability after several adsorption/desorption cycles. The XRD pattern and SEM micrographs resulted in an average size of NPs of 12.2 nm. Regarding the removal of MB from an aqueous solution, the kinetic and isotherm adsorption behavior is governed by the pseudo-second-order model and a Langmuir isotherm which describes an ionic exchange and chemisorption process between the positive partial charges of MB and Vg compounds stabilizing Fe 3 O 4 NPs following a thermodynamically favorable process. Therefore, the green synthesis of NPs from Vg leaf extract is considered a sustainable alternative to removing dyes from aqueous solutions.

Keywords: magnetic nanoparticles; Vallesia glabra; cationic dye; adsorption; green synthesis (search for similar items in EconPapers)
JEL-codes: O13 Q Q0 Q2 Q3 Q5 Q56 (search for similar items in EconPapers)
Date: 2023
References: View complete reference list from CitEc
Citations: View citations in EconPapers (1)

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