The Effect of Sequential and Simultaneous Supplementation of Waste-Derived Volatile Fatty Acids and Methanol as Alternative Carbon Source Blend for Wastewater Denitrification

Tugba Sapmaz, Reza Manafi, Amir Mahboubi (), Derya Y. Koseoglu-Imer and Mohammad J. Taherzadeh
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Tugba Sapmaz: Swedish Centre for Resource Recovery, University of Borås, 501 90 Borås, Sweden
Reza Manafi: Swedish Centre for Resource Recovery, University of Borås, 501 90 Borås, Sweden
Amir Mahboubi: Swedish Centre for Resource Recovery, University of Borås, 501 90 Borås, Sweden
Derya Y. Koseoglu-Imer: Department of Environmental Engineering, Istanbul Technical University, Istanbul 34469, Turkey
Mohammad J. Taherzadeh: Swedish Centre for Resource Recovery, University of Borås, 501 90 Borås, Sweden

Sustainability, 2023, vol. 15, issue 8, 1-16

Abstract: Supplementation of alternative carbon sources is a technological bottleneck, particularly in post-denitrification processes due to stringent effluent nitrogen levels. This study focuses on enhancing the sustainability of wastewater treatment practices by partially replacing conventionally used fossil-derived methanol with organic waste-derived volatile fatty acids (VFAs) in moving bed biofilm reactors (MBBRs). In this regards, results of denitrification batch assays with sequential or simultaneous addition of VFA effluent from acidogenic fermentation of potato starch residue (AD-VFA PPL ) and chicken manure (AD-VFA CKM ), simulated synthetic VFAs solutions (sVFAs), and methanol as carbon source were presented and discussed. Although methanol has proven superior in the conversion of nitrate to nitrite, VFAs are more effective when it comes to reducing nitrite. Although solely added AD-VFA PPL had a slower denitrification capability (0.56 ± 0.13 mgNO x -N removed/m 2 /day) than methanol (1.04 ± 0.46 mgNO x -N removed/m 2 /day), up to 50% of the methanol can be replaced by waste-derived AD-VFA PPL and achieve comparable performance (1.08 ± 0.07 mgNO x -N removed/m 2 /day) with the pure methanol. This proves that the co-addition of VFAs together with methanol can fully compete with pure methanol in performance, providing a promising opportunity for wastewater treatment plants to potentially reduce their carbon footprint and become more sustainable in practice while benefiting from recovered nutrients from waste.

Keywords: volatile fatty acids; post-denitrification; moving bed biofilm reactor; carbon source; chicken manure; potato protein liquor; ethanol; methanol (search for similar items in EconPapers)
JEL-codes: O13 Q Q0 Q2 Q3 Q5 Q56 (search for similar items in EconPapers)
Date: 2023
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