Fabrication and Characterization of Pt-Pr 6 O 11 Nano Cathode Electrode for Polymer Electrolyte Membrane Fuel Cells via Co-Sputtering Method

Ki Won Hong, Ye Rim Kwon, Dong Kun Song, Do Yeong Jung, Byung Kyu Kang, Soon Ki Kwon, Sangbong Ryu () and Gu Young Cho ()
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Ki Won Hong: Department of Mechanical Engineering, Dankook University, 152 Jukjeon-ro, Suji-gu, Yongin-si 16890, Gyeonggi-di, Republic of Korea
Ye Rim Kwon: Department of Mechanical Engineering, Dankook University, 152 Jukjeon-ro, Suji-gu, Yongin-si 16890, Gyeonggi-di, Republic of Korea
Dong Kun Song: Department of Mechanical Engineering, Dankook University, 152 Jukjeon-ro, Suji-gu, Yongin-si 16890, Gyeonggi-di, Republic of Korea
Do Yeong Jung: Department of Mechanical Engineering, Dankook University, 152 Jukjeon-ro, Suji-gu, Yongin-si 16890, Gyeonggi-di, Republic of Korea
Byung Kyu Kang: Department of Mechanical Engineering, Dankook University, 152 Jukjeon-ro, Suji-gu, Yongin-si 16890, Gyeonggi-di, Republic of Korea
Soon Ki Kwon: Department of Mechanical Engineering, Dankook University, 152 Jukjeon-ro, Suji-gu, Yongin-si 16890, Gyeonggi-di, Republic of Korea
Sangbong Ryu: Energy and Environment Directorate, Pacific Northwest National Laboratory, 902 Battelle Boulevard, Richland, WA 99354, USA
Gu Young Cho: Department of Mechanical Engineering, Dankook University, 152 Jukjeon-ro, Suji-gu, Yongin-si 16890, Gyeonggi-di, Republic of Korea

Sustainability, 2024, vol. 17, issue 1, 1-12

Abstract: In this study, the performance and durability of polymer electrolyte membrane fuel cells (PEMFCs) were improved using a Pt-Pr 6 O 11 composite electrode fabricated through a co-sputtering technique. Platinum (Pt), widely used as the catalyst material in PEMFCs, often faces stability issues under various electrical load conditions. These issues require greater efforts to enhance PEMFC durability. Various approaches, including replacement of catalyst supports with electrically stable materials (such as metal oxides) or adoption of core-shell and alloy structures to stabilize Pt, have been attempted. In this research, a thin film electrode combining Pr 6 O 11 and Pt was fabricated. Pr 6 O 11 , a lanthanide oxide, enhances the oxygen reduction reaction (ORR) through strong interactions with Pt, and its multi-valence state contributes to improved durability. Scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS) were employed to analyze the composition, morphology, and chemical characteristics of the electrodes. I-V curves and electrochemical impedance spectroscopies (EIS) were measured to evaluate electrochemical properties of fuel cells. A cyclic voltammetry (CV) test was conducted to calculate the electrochemical surface area of the cell. As a result, the incorporation of Pr 6 O 11 improved the pristine cell performance by 7.6% and increased performance after degradation testing by 121% compared to Pt-only cases. This demonstrates the effectiveness of the Pt-Pr 6 O 11 composite in enhancing both the initial performance and the durability of PEMFCs.

Keywords: polymer electrolyte membrane fuel cell; co-sputtering; praseodymium oxide; oxygen reduction reaction; cathode electrode; durability; electrochemical performance; degradation test (search for similar items in EconPapers)
JEL-codes: O13 Q Q0 Q2 Q3 Q5 Q56 (search for similar items in EconPapers)
Date: 2024
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