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Exclusive and ultrasensitive detection of formaldehyde at room temperature using a flexible and monolithic chemiresistive sensor

Yong Kun Jo, Seong-Yong Jeong, Young Kook Moon, Young-Moo Jo, Ji-Wook Yoon and Jong-Heun Lee ()
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Yong Kun Jo: Korea University
Seong-Yong Jeong: Korea University
Young Kook Moon: Korea University
Young-Moo Jo: Korea University
Ji-Wook Yoon: Jeonbuk National University
Jong-Heun Lee: Korea University

Nature Communications, 2021, vol. 12, issue 1, 1-9

Abstract: Abstract Formaldehyde, a probable carcinogen, is a ubiquitous indoor pollutant, but its highly selective detection has been a long-standing challenge. Herein, a chemiresistive sensor that can detect ppb-level formaldehyde in an exclusive manner at room temperature is designed. The TiO2 sensor exhibits under UV illumination highly selective detection of formaldehyde and ethanol with negligible cross-responses to other indoor pollutants. The coating of a mixed matrix membrane (MMM) composed of zeolitic imidazole framework (ZIF-7) nanoparticles and polymers on TiO2 sensing films removed ethanol interference completely by molecular sieving, enabling an ultrahigh selectivity (response ratio > 50) and response (resistance ratio > 1,100) to 5 ppm formaldehyde at room temperature. Furthermore, a monolithic and flexible sensor is fabricated successfully using a TiO2 film sandwiched between a flexible polyethylene terephthalate substrate and MMM overlayer. Our work provides a strategy to achieve exclusive selectivity and high response to formaldehyde, demonstrating the promising potential of flexible gas sensors for indoor air monitoring.

Date: 2021
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DOI: 10.1038/s41467-021-25290-3

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