Spatiotemporal control of photochromic upconversion through interfacial energy transfer

Long Yan, Jinshu Huang, Zhengce An, Qinyuan Zhang and Bo Zhou ()
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Long Yan: South China University of Technology
Jinshu Huang: South China University of Technology
Zhengce An: South China University of Technology
Qinyuan Zhang: South China University of Technology
Bo Zhou: South China University of Technology

Nature Communications, 2024, vol. 15, issue 1, 1-9

Abstract: Abstract Dynamic control of multi-photon upconversion with rich and tunable emission colors is stimulating extensive interest in both fundamental research and frontier applications of lanthanide based materials. However, manipulating photochromic upconversion towards color-switchable emissions of a single lanthanide emitter is still challenging. Here, we report a conceptual model to realize the spatiotemporal control of upconversion dynamics and photochromic evolution of Er3+ through interfacial energy transfer (IET) in a core-shell nanostructure. The design of Yb sublattice sensitization interlayer, instead of regular Yb3+ doping, is able to raise the absorption capability of excitation energy and enhance the upconversion. We find that a nanoscale spatial manipulation of interfacial interactions between Er and Yb sublattices can further contribute to upconversion. Moreover, the red/green color-switchable upconversion of Er3+ is achieved through using the temporal modulation ways of non-steady-state excitation and time-gating technique. Our results allow for versatile designs and dynamic management of emission colors from luminescent materials and provide more chances for their frontier photonic applications such as optical anti-counterfeiting and speed monitoring.

Date: 2024
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DOI: 10.1038/s41467-024-46228-5

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