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STUDY OF MICROSTRUCTURE AND CATALYTIC ACTIVITY OFγ-Bi2MoO6ANDBi2WO6COMPOUNDS

R. Rangel (), P. Bartolo-Pérez, A. Gómez-Cortéz, G. Díaz and D. H. Galván
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R. Rangel: Facultad de Ingeniería Química, Universidad Michoacana de SNH, Edificio "K" Ciudad Universitaria, 58060, Morelia, Mich., Mexico
P. Bartolo-Pérez: Departamento de Física Aplicada, Centro de Investigación y de Estudios Avanzados del IPN, Apartado Postal 73 Cordemex, 97310, Mérida, Yucatán, Mexico
A. Gómez-Cortéz: Instituto de Física, Universidad Nacional Autónoma de México, Apartado Postal 20-364, 01000, Mexico, DF, Mexico
G. Díaz: Instituto de Física, Universidad Nacional Autónoma de México, Apartado Postal 20-364, 01000, Mexico, DF, Mexico
D. H. Galván: Centro de Ciencias de la Materia Condensada, Universidad Nacional Autónoma de México, Apartado Postal 2681, 22800, Ensenada, BC, Mexico

Surface Review and Letters (SRL), 2002, vol. 09, issue 05n06, 1779-1783

Abstract: Bi2MO6(M=Mo, W) compounds were prepared for low-temperature oxidation. The catalysts were prepared by solid-state reaction. The structural changes were followed by X-ray diffraction, scanning electron microscopy, Auger electron spectroscopy and BET nitrogen absorption. Auger analysis shows thatBi2WO6catalysts have more bismuth on the surface thanγ-Bi2MoO6, although both samples are bismuth deficient as compared to the stoichiometric compound. The results regarding catalytic activity show thatBi2WO6prepared at 1073 K reaches total conversion of CO (100%) at a lower temperature when compared toγ-Bi2MoO6. This indicates thatBi2WO6is a potential candidate to be used as catalyst in the CO toCO2oxidation.

Date: 2002
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DOI: 10.1142/S0218625X02004402

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