Spectral Investigation of Physical Adsorption in Porous Glass

Andriy Dmytruk and Volodymyr Ovechko
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Andriy Dmytruk: Radiophysical Faculty, National Taras Shevchenko University of Kyiv, Academician Glushkov Prospect, 2/5, Kyiv 03122, Ukraine
Volodymyr Ovechko: Radiophysical Faculty, National Taras Shevchenko University of Kyiv, Academician Glushkov Prospect, 2/5, Kyiv 03122, Ukraine

Surface Review and Letters (SRL), 2003, vol. 10, issue 02n03, 289-293

Abstract: An oscillators model of physical adsorption on a silica surface has been built considering the molecular adsorbent-adsorbate complex as two relatively individual parts united by a weak van der Waals interaction. An experimental study of the NIR spectra of ammonia andp-xylene molecules adsorbed in a porous glass has been carried out. Theory and experiment agree well.

Date: 2003
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DOI: 10.1142/S0218625X03005517

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