Effect of oxygen enrichment on acid gas combustion in hydrogen/air flames under claus conditions

H. Selim, S. Ibrahim, A. Al Shoaibi and A.K. Gupta

Applied Energy, 2013, vol. 109, issue C, 119-124

Abstract: Results are presented to examine the combustion of acid gas (H2S and CO2) in hydrogen-fueled flames using a mixture of oxygen and nitrogen under Claus conditions (Φ=3). Specifically the effect of oxygen enrichment in the above flames is examined. The compositions of acid gas examined are100% H2S and 50% H2S/50% CO2 with different percentages of oxygen enrichment (0%, 19.3% and 69.3%) in the oxygen/nitrogen mixtures. The results revealed that combustion of acid gas formed SO2 wherein the mole fraction of SO2 increased to an asymptotic value at all the oxygen concentrations examined. In addition, increase in oxygen enrichment of the air resulted in increased amounts of SO2 rather than the formation of more desirable elemental sulfur. In case of 50% H2S/50% CO2 acid gas, carbon monoxide mole fraction increased with oxygen enrichment which is an indicator to the availability of additional amounts of oxygen into the reaction pool. This gas mixture resulted in the formation of other sulfurous–carbonaceous compounds (COS and CS2) due to the presence of carbon monoxide. The results showed that the rate of COS formation increased with oxygen enrichment due to the availability of higher amounts of CO while that of CS2 reduced. The global reactions responsible for this observed phenomenon are presented.

Keywords: Hydrogen sulfide; Claus process; Sulfur chemistry; Oxygen enrichment in claus process; Chemical kinetics (search for similar items in EconPapers)
Date: 2013
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (8)

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0306261913002225
Full text for ScienceDirect subscribers only

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:appene:v:109:y:2013:i:c:p:119-124

Ordering information: This journal article can be ordered from
http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/bibliographic
http://www.elsevier. ... 405891/bibliographic

DOI: 10.1016/j.apenergy.2013.03.026

Access Statistics for this article

Applied Energy is currently edited by J. Yan

More articles in Applied Energy from Elsevier
Bibliographic data for series maintained by Catherine Liu ().