Preparation and thermal properties of palmitic acid/polyaniline/exfoliated graphite nanoplatelets form-stable phase change materials
Ju-Lan Zeng,
Shuang-Hao Zheng,
Sai-Bo Yu,
Fu-Rong Zhu,
Juan Gan,
Ling Zhu,
Zhong-Liang Xiao,
Xin-Yu Zhu,
Zhen Zhu,
Li-Xian Sun and
Zhong Cao
Applied Energy, 2014, vol. 115, issue C, 603-609
Abstract:
Exfoliated graphite nanoplatelets (xGnP) were applied to enhance the thermal conductivity of polyaniline (PANI) based form-stable phase change materials (PCMs). The xGnP was first dispersed in palmitic acid (PA) uniformly under the assistance of ultra-sonication. The xGnP/PA mixture was then applied to prepare PA/PANI/xGnP form-stable PCMs, in which PANI was obtained by means of surface polymerization of aniline and acted as supporting material. The content of PA in the prepared form-stable PCMs was fixed as 75wt%. The structure, thermal energy storage properties and thermal conductivity of the PA/PANI/xGnP form-stable PCMs were investigated. The results showed that the thermal conductivity of the prepared form-stable PCMs could be greatly improved by xGnP while the thermal energy storage capacity was maintained. The thermal conductivity and thermal energy storage capacity of the PA/PANI/xGnP form-stable PCM doped with 7.87wt% of xGnP could attain 1.08W/(mK) and 157.7J/g, respectively. The thermal conductivity was 237.5% higher than that of PA/PANI form-stable PCM. The prepared PA/PANI/xGnP form-stable PCM is expected to exhibit better performance in solar thermal energy applications.
Keywords: Form-stable phase change materials; Solar energy; Thermal energy storage; Exfoliated graphite nanoplatelets; Thermal conductivity (search for similar items in EconPapers)
Date: 2014
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Citations: View citations in EconPapers (12)
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DOI: 10.1016/j.apenergy.2013.10.061
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