Conversion of metallurgical coke and coal using a Coal Direct Chemical Looping (CDCL) moving bed reactor

Siwei Luo, Samuel Bayham, Liang Zeng, Omar McGiveron, Elena Chung, Ankita Majumder and Liang-Shih Fan

Applied Energy, 2014, vol. 118, issue C, 300-308

Abstract: The CLC process has the potential to be a transformative commercial technology for a carbon-constrained economy. The Ohio State University Coal Direct Chemical Looping (CDCL) process directly converts coal, eliminating the need for a coal gasifier oran air separation unit (ASU). Compared to other solid-fuel CLC processes, the CDCL process is unique in that it consists of a countercurrent moving bed reducer reactor. In the proposed process, coal is injected into the middle of the moving bed, whereby the coal quickly heats up and devolatilizes, splitting the reactor roughly into two sections with no axial mixing. The top section consists of gaseous fuel produced from the coal volatiles, and the bottom section consists of the coal char mixed with the oxygen carrier. A bench-scale moving bed reactor was used to study the coal conversion with CO2 as the enhancing gas. Initial tests using metallurgical cokefines as feedstock were conducted to test the effects of operational variables in the bottom section of the moving bed reducer, e.g., reactor temperature, oxygen carrier to char ratio, enhancer gas CO2 flow rate, and oxygen carrier flow rates. Experiments directly using coal as the feedstock were subsequently carried out based on these test results. Powder River Basin (PRB) coal and Illinois #6 coal were tested as representative sub-bituminous and bituminous coals, respectively. Nearly complete coal conversion was achieved using composite iron oxide particles as the oxygen carriers without any flow problems. The operational results demonstrated that a moving bed reactor design is favorable for the CDCL application.

Keywords: Chemical Looping Combustion; Coal; Metallurgical coke; CO2capture; Moving bed; Energy (search for similar items in EconPapers)
Date: 2014
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Citations: View citations in EconPapers (10)

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DOI: 10.1016/j.apenergy.2013.11.068

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