Investigation of enhanced thermal properties in NiO-based nanofluids for concentrating solar power applications: A molecular dynamics and experimental analysis

Teresa Aguilar, Javier Navas, Antonio Sánchez-Coronilla, Elisa I. Martín, Juan Jesús Gallardo, Paloma Martínez-Merino, Roberto Gómez-Villarejo, José Carlos Piñero, Rodrigo Alcántara and Concha Fernández-Lorenzo

Applied Energy, 2018, vol. 211, issue C, 677-688

Abstract: Nanofluids could be a promising alternative to the typical heat transfer fluids (HTF) used in concentrating solar power. This study analyses nanofluids based on a typical HTF for concentrating solar power (CSP) applications and NiO nanoparticles. The optimum nanoparticle concentration was determined by analysing the stability of the nanofluids. Some of their properties, such as density, viscosity, isobaric specific heat and thermal conductivity, were characterized to evaluate their performance. Their thermal conductivity increased by up to 96% and the heat transfer coefficient by 50%. Molecular dynamics calculations were performed to explain from a molecular perspective how the presence of equal proportions of two surfactants, benzalkonium chloride (BAC) and 1-Octadecanethiol (ODT), enhanced the thermal properties of the NiO nanofluid. The isobaric specific heat and thermal conductivity values followed the same experimental tendency. The analysis of the radial distribution functions (RDFs) and spatial distribution functions (SDFs) revealed an inner layer of base fluid and surfactant molecules around the NiO cell. This first layer contained BAC molecules at all the temperatures, while ODT was only incorporated at higher temperatures. The exchange of surfactant and base fluid molecules around the NiO as the temperature increases may play an important role in the enhancement of the thermal properties.

Keywords: Concentrating solar power; Solar energy; Nanofluid; Thermal properties; Molecular dynamics (search for similar items in EconPapers)
Date: 2018
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Citations: View citations in EconPapers (8)

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DOI: 10.1016/j.apenergy.2017.11.069

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