Improved methods to measure hydrogen crossover current in proton exchange membrane fuel cell

Pucheng Pei, Ziyao Wu, Yuehua Li, Xiaoning Jia, Dongfang Chen and Shangwei Huang

Applied Energy, 2018, vol. 215, issue C, 338-347

Abstract: Hydrogen crossover current has a great influence on the performance and durability of proton exchange membrane (PEM) fuel cells. The common measuring method is linear sweep voltammetry (LSV). But some usual approximations, such as ignoring the influence of scan rates or short-circuit resistances, can lead to greater measurement deviations. Therefore, in this study to accurately measure hydrogen crossover current, LSV is improved by building a novel charging model based on fitted zero scan rate curves and on taking effects of short circuit into consideration. On the basis of this new model, galvanostatic charging method is improved by taking short circuit of PEMs into consideration and a mass spectrometry assisted with hydrogen pump is proposed with no need of calibration with standard gas. Hydrogen crossover current and short-circuit resistance of a 34 cm2 single cell are measured by three improved methods, which are then compared with methods previously available. It is found that hydrogen crossover currents are reduced and more accurate than those obtained by previous methods, and values obtained by different improved methods are highly consistent with each other. So the proposed charging model is valid and can be used to optimize other electrochemical measurements of fuel cells.

Keywords: Proton exchange membrane fuel cell; Hydrogen crossover current; Short-circuit resistance; Linear sweep voltammetry; Galvanostatic charge method; Mass spectrometry (search for similar items in EconPapers)
Date: 2018
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (13)

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DOI: 10.1016/j.apenergy.2018.02.002

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