Two-train elevated-temperature pressure swing adsorption for high-purity hydrogen production

Xuancan Zhu, Yixiang Shi, Shuang Li and Ningsheng Cai

Applied Energy, 2018, vol. 229, issue C, 1071 pages

Abstract: The trade-off between hydrogen recovery ratio (HRR) and hydrogen purity (HP) is one of the main drawbacks in normal temperature pressure swing adsorption (NT-PSA) for producing high-purity hydrogen from shifted gas. In this paper, a two-train elevated-temperature pressure swing adsorption (ET-PSA) process that achieved 99.999% HP and over 95% HRR is proposed, which has wide application potentials in fuel cells and chemical industries. Potassium-promoted layered double oxide (K-LDO), which shows reasonable working capacity and fast adsorption/desorption kinetics at elevated temperatures (200–450 °C), is adopted as the CO2 adsorbent. CO in the shifted gas is co-purified by high-temperature water gas shift (WGS) catalysts added to the columns. The first-train ET-PSA adopted an eight-column thirteen-step configuration with shorter step time to remove most of the CO/CO2 in the shifted gas, and the second-train ET-PSA adopted a double-column seven-step configuration with longer step time to purify the residual gas impurities. The introduction of co-current high-pressure steam rinse and counter-current low-pressure steam purge is the key to achieve both high HRR and HP. The high-temperature steam is the main energy consumption of ET-PSA rather than low HRR in NT-PSA, and the total steam consumption is reduced by adopting the tail gas from second-train ET-PSA as the purge gas for first-train ET-PSA. The optimal results achieved 97.51% HRR and 99.9994% HP with only 0.188 rinse-to-feed ratio and 0.263 purge-to-feed ratio, which are the highest values reported for PSAs producing high-purity hydrogen from carbon-based fuels.

Keywords: Elevated-temperature pressure swing adsorption; Potassium-promoted layered double oxide; Hydrogen production; Shifted gas (search for similar items in EconPapers)
Date: 2018
References: View references in EconPapers View complete reference list from CitEc
Citations: View citations in EconPapers (8)

Downloads: (external link)
http://www.sciencedirect.com/science/article/pii/S0306261918312649
Full text for ScienceDirect subscribers only

Related works:
This item may be available elsewhere in EconPapers: Search for items with the same title.

Export reference: BibTeX RIS (EndNote, ProCite, RefMan) HTML/Text

Persistent link: https://EconPapers.repec.org/RePEc:eee:appene:v:229:y:2018:i:c:p:1061-1071

Ordering information: This journal article can be ordered from
http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/bibliographic
http://www.elsevier. ... 405891/bibliographic

DOI: 10.1016/j.apenergy.2018.08.093

Access Statistics for this article

Applied Energy is currently edited by J. Yan

More articles in Applied Energy from Elsevier
Bibliographic data for series maintained by Catherine Liu ().